Potentiometric sensors for trace-level analysis
نویسندگان
چکیده
منابع مشابه
Modern Directions for Potentiometric Sensors.
This paper gives an overview of the newest developments of polymeric membrane ion-selective electrodes. A short essence of the underlying theory is given, emphasizing how the electromotive force may be used to assess binding constants of the ionophore, and how the selectivity and detection limit are related to the underlying membrane processes. The recent developments in lowering the detection ...
متن کاملRational design of potentiometric trace level ion sensors. A Ag+-selective electrode with a 100 ppt detection limit.
Submicromolar to picomolar lower detection limits have recently been obtained with various polymer membrane ion-selective electrodes by minimizing biases due to ion fluxes through the membrane. For the best performance, the compositions of the membrane and inner solution should be optimized for each application. Given the number of parameters to be adjusted, it has been difficult to find the be...
متن کاملScreen Printed Potentiometric Chloride Sensors
Potentiometric chloride sensors were fabricated by electrochemically chloridizing the surface of screen printed silver electrodes using amperostatic coulometry or asymmetric square wave voltammetry. In the case of coulometric chloridization, the effect of different chloride ion sources was also investigated. The response to chloride ions by each type of sensor was determined by measuring their ...
متن کاملSpray-coated all-solid-state potentiometric sensors.
A novel fully spray coating-based method of the preparation of all-solid-state ion-selective electrodes of simplified construction is proposed. This method is an alternative for screen-printed electrodes used sometimes in potentiometric applications. The benefits of the herein-proposed approach include fully automatic sensor preparation and minimized use of chemicals allowing for the production...
متن کاملApplicationsof Potentiometric Sensors in Nonaqueous Solutions
Current trends in electrochemical studies of nonaqueous solutions are discussed with the emphasis on experimental approaches judged to be particularly promising for the future development of both fundamental and applied aspects of the field of solution chemistry. Topics include recent developments in the application of potentio— metric sensors to nonaqueous solutions, the potentialities of such...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: TrAC Trends in Analytical Chemistry
سال: 2005
ISSN: 0165-9936
DOI: 10.1016/j.trac.2005.01.003